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空間原子氧對低地球軌道航天器用粘結(jié)劑的腐蝕效應(yīng)影響(英文)

The effects of space atomic oxygen erosion on epoxy and silicone adhesives in LEO spacecraft

  • 摘要: 原子氧是低地球軌道(LEO)一種重要的空間環(huán)境因素,地面模擬試驗是用于開展LEO航天器備選材料原子氧環(huán)境評價的主要手段。利用北京衛(wèi)星環(huán)境研究所的原子氧設(shè)備,對牌號為E-32的環(huán)氧樹脂和牌號為GS414的硅橡膠兩種粘結(jié)劑進行了評價試驗。依據(jù)軌道參數(shù)與航天器兩年的設(shè)計壽命,選定試驗中原子氧的等效積分通量為1.4×1021 atom/cm2。試驗結(jié)果表明,環(huán)氧樹脂樣品出現(xiàn)了較大的質(zhì)量損失,而硅橡膠樣品的質(zhì)量損失則相對較小。根據(jù)質(zhì)量損失計算環(huán)氧樹脂樣品的原子氧反應(yīng)率處于3.2×10-24~3.8×10-24 cm3/atom之間。試驗后的環(huán)氧樹脂樣品表面顏色變淺,硅橡膠樣品的表面則呈現(xiàn)了玻璃化。對兩種材料都進行了表面形貌分析,試驗前后測試結(jié)果的對比分析表明原子氧的氧化作用使材料表面發(fā)生了較大的變化。

     

    Abstract: Atomic oxygen (AO) is prevalent in Low Earth Orbit (LEO). Ground-based testing on AO exposure was performed to investigate the effects of atomic oxygen on materials to be used in LEO spacecraft. Two types of adhesive materials, E-32 epoxy and GS414 silicone, were tested in the atomic oxygen testing facility at Beijing Institute of Spacecraft Environment Engineering (BISEE). The equivalent atomic oxygen fluence in test was approximately 1.4×1021 atom/cm2 as determined based on two years’ exposure on LEO. Significant mass losses of the epoxy adhesive samples were observed after the exposure to atomic oxygen, but relatively small mass changes were found in the silicone samples. The erosion yields of epoxy samples range from 3.2×10-24 cm3/atom to 3.8×10-24 cm3/atom. Bleaching by atomic oxygen was found in the epoxy samples. The surface on the silicone sample was glossed after AO exposure. The external appearance of both kinds of materials was analyzed using Scanning Electron Microscope (SEM) and X-ray Photoelectron Spectroscopy (XPS). A comparison between unexposed and exposed samples shows noticeable changes on the surface of materials.

     

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