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原子氧環(huán)境下磁力矩器用聚合物材料的質(zhì)損和紅外光譜分析

FT-IR and mass loss analysis of polymer materials in magnetic torquer after atomic oxygen exposure

  • 摘要: 文章利用新型的原子氧環(huán)境模擬設(shè)備進(jìn)行真空和原子氧試驗(yàn),通過質(zhì)量損失測(cè)量和FT-IR分析,對(duì)試樣的質(zhì)量損失率(SAML)和表面成分的變化進(jìn)行了研究。試驗(yàn)結(jié)果表明:真空環(huán)境會(huì)導(dǎo)致材料產(chǎn)生質(zhì)量損失,4種材料中真空質(zhì)損最大相差24倍;原子氧作用導(dǎo)致聚合物材料產(chǎn)生質(zhì)量損失,4種材料中質(zhì)量損失率最大相差25倍;原子氧與有機(jī)硅物質(zhì)反應(yīng)能夠形成保護(hù)層,可以抑制原子氧對(duì)材料內(nèi)部的進(jìn)一步侵蝕。FT-IR分析結(jié)果表明,原子氧作用導(dǎo)致環(huán)氧材料的-N消失,O元素百分比含量升高,硅橡膠的化學(xué)鍵被破壞,并導(dǎo)致新的O-H和C-H的生成。

     

    Abstract: A new kind of atomic oxygen simulator is used to test materials used in the magnetic torquer in this paper. Mass loss measurement and FT-IR analysis are used to obtain SAML and surface composition change of samples. Results indicate that vacuum exposure will lead to mass loss of materials, but the extent of loss for four tested materials sees a huge difference up to twenty four times. As for the mass loss after atomic oxygen exposure, the difference of the extent reaches twenty five times. Silicone can react with atomic oxygen to form a protective coating for preventing more atomic oxygen erosion. FT-IR analysis indicates that nitrogen group disappears on the surface of epoxy after atomic oxygen exposure, and O content increases. For silicone, the chemical bonds are broken and are turned into new kinds of O-H and C-H bonds.

     

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